CHME 2308 board Conservation Principles
CHME 2308, Northeastern University

What does it mean to be a chemical engineer? This is the class where we begin to address that. It has to do with relating systems of algebraic equations to situations found in the real world. Once established, this coupling between the world and mathematics allows us to analyze processes, using two important concepts: conservation of mass and conservation of energy. What is a process? Lots of things qualify as “processes,” and that is another major topic we address.
CHME 2308 board Electrochemical Engineering
CHME 5621, Northeastern University

Electrochemistry is fundamentally an interfacial science, dealing with reactions that happen between an electrode and electrolyte. At this interface, there is a nm-scale separation of charge (the double layer) and a micron-scale concentration gradient (the mass transport boundary layer). Cell performance may be limited by reaction kinetics across the double layer or transport phenomena across the boundary layer. This class is almost always about figuring out which one. Through the lens of chemical engineering fundamentals, we discuss batteries, fuel cells, electrodeposition, and the process of corrosion.
CHME 2308 board Clear Science

I used to write a blog called Clear Science which was one of the first science blogs on Tumblr. Clear Science was dedicated to straightforward science lessons in plain English everyone could understand. The blog was most active from 2010 to 2013, and had over 130,000 followers. I eventually got too busy to keep it up, but I value the lessons it taught me in how to communicate science, especially to a young audience. Some posts turned into larger projects, such as this one about aluminum, which eventually became an hour lecture I used to give to the freshman engineering students at NYU. It also had a nice collection of 40s and 50s black and white science pictures, which I like.

Recent Posts

Bi Enables the Formation of Disordered Birnessite in Rechargeable Alkaline Batteries

We have a new paper out in the Journal of the Electrochemical Society, written by Andrea Bruck. It continues our work on full 617 mAh/g rechargeability of MnO2 in alkaline batteries. Getting that full capacity reversibly enables a design pathway to get very inexpensive ($50/kWh) and high energy density (200 Wh/L) aqueous electrolyte rechargeable Zn-MnO2 batteries for the power grid. Aqueous electrolytes are desirable as an alternative to Li-ion batteries, which have flammable electrolytes, and become more of a safety risk at large scales.

Our main finding is the identification of an amorphous or “disordered” intermediate species during cycling. The figure above shows the voltage profile of the MnO2 cathode during cycling, and each section is labeled with the major material compound that is formed during that stage. (The discharge stages are labeled d1, d2, and d3. Likewise the charging stages are c1, c2, and c3.) We mix the MnO2 with bismuth oxide or Bi2O3, which is what makes it rechargeable. And during step c2, we have demonstrated a disordered compound we had never seen before. The reason we had never seen it is because all the other compounds are crystalline, and crystalline things are very easy to see. Disordered (or non-crystalline) things are often more challenging to put your finger on.

The figure above shows the structure of the layered birnessite or ẟ-MnO2, which consists of [MnO6] slabs separated by an interlayer. This data is from X-ray diffraction (XRD), which uses long-range crystallinity to produce a material fingerprint. This fingerprint is in the form of peaks or reflections, and the plot has the experimental data (black) compared to a theoretical calculation (red). We used a method called Rietveld refinement to match these and get the coordinates for all of the atoms in the material. (For example, we can tell the birnessite is hexagonal and the slab-to-slab distance is 7.131 Å)

However, you can’t observe a material by XRD if it doesn’t have good crystallinity, a.k.a. the “long-range order” to diffract X-rays. Instead we used operando Raman spectroscopy, which fingerprints materials using their response to a laser. Birnessite materials result in a series of Raman vibrational bands, the largest of which are ν1 and ν2. The figure above shows the Raman spectrum during the charge step both without Bi (top) and with Bi (bottom). In the top plots, the ν1 and ν2 bands didn’t appear until the blue dot, which is the c3 stage. However, with Bi, they appeared very early, even before the red dot, which is in the c2 stage. We know this is a disordered birnessite because it was not visible to XRD, but showed up clearly with Raman spectroscopy.

This is exciting because no one really knows why Bi makes birnessite rechargeable. Since we see it enables this formation of a disordered birnessite, that could be the key.

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